Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 28, Pages 7619-7623Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01121c
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Funding
- National Basic Research Program of China (973 Program) [2011CB808600]
- National Natural Science Foundation of China [21322203, 21272238, 21472194]
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The first C-H aminocarbonylation of azobenzenes with isocyanates is achieved by using rhenium-catalysis, which provides an expedient and atom-economical access to varied o-azobenzamides from readily available starting materials. The reaction efficiency can be enhanced by the catalytic use of sodium acetate via accelerated C-H bond activation.
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