Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 33, Pages 8812-8816Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01301a
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Funding
- Major State Basic Research Development Program of China [2011CB808602]
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Highly enantioselective cyanation of beta-keto esters using hypervalent iodine(III) as the electrophilic cyanating reagent induced by cinchona alkaloid-based chiral quaternary ammonium salt was demonstrated. Organic bases, especially DMAP, in the chiral phase-transfer catalysis were used to obtain high ees.
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