Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 16, Pages 4632-4636Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00378d
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- MEXT
- Grants-in-Aid for Scientific Research [25105737, 15H00750] Funding Source: KAKEN
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We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.
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