Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 21, Pages 5894-5904Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00548e
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- Russian Foundation for Basic Research [15-03-02877, 13-03-12055 ofi_m]
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New water-soluble p-tert-butylthiacalix[4]arenes containing peptide and quaternary ammonium fragments in cone and 1,3-alternate conformations were synthesized and characterized. The interaction of the macrocycles with DNA was studied by UV-spectroscopy, DLS and TEM. It was shown that the interaction of the self-associates based on p-tert-butylthiacalix[4] arenes tetrasubstituted at the lower rim with glycine and quaternary ammonium fragments in cone and 1,3-alternate conformations with DNA led to the formation of particles of about 99-192 nm in size.
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