Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 39, Pages 9963-9968Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01675d
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Funding
- National Natural Science Foundation of China [21472068, 21202062]
- Natural Science Foundation of Jiangsu Province [BK2012108]
- MOE SAFEA [B13025]
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A Cu(I)-catalyzed cyanation reaction of aryl iodides with alpha-cyanoacetates is reported herein, which uses alpha-cyanoacetates as the nontoxic and easy-handling CN source through copper-mediated C-CN bond cleavage. This reaction enables access to aryl nitriles with an array of functional groups on the aromatic ring in good to excellent yields.
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