Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 4, Pages 1048-1052Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob02017k
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Funding
- National University of Singapore
- Ministry of Education (MoE) [R-143-000-478-112]
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A copper-catalyzed method for the oxidation of allylic and benzylic sp(3) C-H by aqueous tert-butyl hydroperoxide (T-Hydro) in water using a recyclable fluorous ligand has been developed. The reaction procedure is tolerant to additional functional groups and the fluorous ligand could be reused with little loss of catalytic activity.
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