Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 9, Pages 2561-2565Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob02355b
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Funding
- National Natural Science Foundation of China [21025207, 21372199]
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The benzylsilver cation which emerges from the collisional dissociation of silver(I)-N-benzylbenzamide complexes was characterized by deuterium-labeling experiments, theoretical calculations, breakdown curves and substituent effects. The nucleophilic attack of the carbonyl oxygen on an alpha-hydrogen results in the generation of the benzylsilver cation, which is competitive to the AgH loss with the alpha-hydrogen.
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