Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 10, Pages 2890-2894Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob02418d
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Funding
- Fundamental Research Funds for the Central Universities [30920130111002]
- National Natural Science Foundation of China [21476116]
- Natural Science Foundation of Jiangsu [BK20141394]
- Center for Advanced Materials and Technology
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An operationally simple and selective method for the direct conversion of benzylic C-H to C-F to obtain mono-and difluoromethylated arenes using Selectfluor (TM) as a fluorine source is developed. Persulfate can be used to selectively activate benzylic hydrogen atoms toward C-F bond formation without the aid of transition metal catalysts.
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