Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 2, Pages 513-519Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob01801j
Keywords
-
Categories
Funding
- Ministry of Education of China [IRT1225]
- National Natural Science Foundation of China [21362002, 41206077, 81260472]
- State Key Laboratory Cultivation Base for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Science and Technology of China [CMEMR2014-A02, CMEMR2012-A, CMEMR2013-C01]
- Bagui Scholar Program of Guangxi
Ask authors/readers for more resources
A novel and highly stereoselective synthesis of Z-beta-enaminonitriles from azides and alpha,beta-unsaturated nitriles is reported. The reaction proceeds via a 1,3-dipolar cycloaddition-ring cleavage-rearrangement cascade mediated by a catalytic amount of Sc(OTf)(3). A plausible reaction mechanism for this process is depicted.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
