Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 15, Pages 4506-4513Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00098j
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Funding
- European Research Council [ERC-StG 279548]
- MINECO [CTQ2011-23659]
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A series of lipophilic nucleosides comprising natural and non-natural bases that are pi-conjugated to a short oligophenylene-ethynylene fragment has been synthesized. These bases comprise guanosine, isoguanosine, and 2-aminoadenosine as purine heterocycles, and cytidine, isocytosine and uridine as complementary pyrimidine bases. The hydrogen-bonding dimerization and association processes between complementary bases were also studied by H-1 NMR and absorption spectroscopy in order to obtain the relevant association constants.
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