4.4 Article

Ionic Liquid Catalyzed Expeditious Synthesis of 2-Aryl-2,3-dihydroquinolin-4(1H)-ones and 2-Aryl-2,3-dihydro-4H-chromen-4-ones under Microwave Irradiation

Journal

JOURNAL OF HETEROCYCLIC CHEMISTRY
Volume 46, Issue 4, Pages 791-795

Publisher

WILEY
DOI: 10.1002/jhet.123

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Funding

  1. BITS, Pilani
  2. DRDO [ERIP/ER/0505034/M/01/902]

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A facile and convenient synthesis of 2-aryl-2,3-dihydroquinolin-4(1H)-one and 2-aryl-2,3-dihydro-4H-chromen-4-one has been described using ionic liquid catalyzed intramolecular cyclization of the corresponding 2'-aminochalcones and 2'-hydroxychalcones, respectively. The rapid and fairly general protocol affords product in good yield. Ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate, was recovered and reused without loosing its efficiency.

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