Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 271, Issue -, Pages 50-56Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2014.02.001
Keywords
Lithium-ion batteries; Recycling; Electric vehicles; Ionic liquid; Fourier's law
Categories
Funding
- National Nature Science Foundation of China [71373141]
- special fund of the State Key Joint Laboratory of Environmental Simulation and Pollution Control [11Z02ESPCT]
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Because of the increasing number of electric vehicles, there is an urgent need for effective recycling technologies to recapture the significant amount of valuable metals contained in spent lithium-ion batteries (LiBs). Previous studies have indicated, however, that Al and cathode materials were quite difficult to separate due to the strong binding force supplied by the polyvinylidene fluoride (PVDF), which was employed to bind cathode materials and Al foil. This research devoted to seek a new method of melting the PVDF binder with heated ionic liquid (IL) to separate Al foil and cathode materials from the spent high-power LiBs. Theoretical analysis based on Fourier's law was adopted to determine the heat transfer mechanism of cathode material and to examine the relationship between heating temperature and retention time. All the experimental and theoretic results show that peel-off rate of cathode materials from Al foil could reach 99% when major process parameters were controlled at 180 degrees C heating temperature, 300 rpm agitator rotation, and 25 min retention time. The results further imply that the application of IL for recycling Al foil and cathode materials from spent high-power LiBs is highly efficient, regardless of the application source of the LiBs or the types of cathode material. This study endeavors to make a contribution to an environmentally sound and economically viable solution to the challenge of spent LiB recycling. (C) 2014 Elsevier B.V. All rights reserved.
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