Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 260, Issue -, Pages 569-575Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2013.05.056
Keywords
NF-TiO2; Amitrole; Atrazine; Peroxymonosulfate; Persulfate
Categories
Funding
- Cyprus Research Promotion Foundation
- Republic of Cyprus
- European Regional Development Fund of the EU [NEA/IPODOMI/STRATH/0308/09]
- National Science Foundation US-Ireland CBET [1033317]
- National Science Foundation Trainee in the Applied Membrane Science and Technology Summer Site Program at the University of Cincinnati (NSF EEC Award) [0647677]
- Liaoning Province Natural Science Fund Project of China [201202091]
- Science Research Plan Project of Liaoning Province Education Department of China [L2012006]
- Project of Liaoning University of China
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1033317] Funding Source: National Science Foundation
- Directorate For Engineering
- Div Of Engineering Education and Centers [0647677] Funding Source: National Science Foundation
Ask authors/readers for more resources
In order to investigate sustainable alternatives to current water treatment methods, the effect of NF-titania film thickness and subsequent photocatalysis in combination with oxidants was examined under simulated solar light. Such a combination presents a theoretical possibility for a synergistic interaction between the photocatalyst and the oxidant (activation of the oxidant by the catalyst under conditions under which it may not conventionally be activated). To investigate, peroxymonosulfate (PMS) and persulfate (PS) were used as oxidants, and two pesticides, amitrole and atrazine, were used as target contaminants. In the absence of a film, activation of PMS under simulated solar conditions is demonstrated by removal of atrazine, whereas PS provided minimal removal, suggesting inefficient activation. Combining photocatalytic films with PMS and PS manifested synergies for both oxidants. The effect was most pronounced for PS since PMS already underwent significant activation without the photocatalyst. Amitrole degradation results indicated a lack of removal of amitrole by activated PS alone, suggesting that this sulfate radical-based treatment technology may be ineffective for the removal of amitrole. The NF-TiO2 films demonstrated reusability under solar light both with and without oxidants. Finally, the degradation intermediates were analyzed, and a new intermediate appeared upon incorporating oxidants into the system. (C) 2013 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available