Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 211, Issue -, Pages 88-94Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2011.08.074
Keywords
Visible light activity; N-doping; Photocatalytic activity; Band gap widening; Degussa p25; Mechanism of doping; Semiconductor photocatalysis; Sol-gel and TiO2
Categories
Funding
- Science Foundation Ireland (SFI) [10/US/I1822]
- CREST
- Focas for lab and office facilities and equipment
- Enterprise Ireland [CFTD/06/IT/326, ARE/2008/0005]
- Environmental Protection Agency (EPA) Ireland
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1033317] Funding Source: National Science Foundation
Ask authors/readers for more resources
In order to study the visible light photocatalytic activity of nitrogen doped titanium dioxide, the interaction between nitrogen dopant sources and titania precursors during sot-gel synthesis is investigated. N-TiO2 was synthesised using the sol-gel method using 1,3-diaminopropane as a nitrogen source. Samples were annealed several temperatures and the percentage of rutile present determined by X-ray diffraction to be 0% (500 degrees C), 46% (600 degrees C), and 94% (700 degrees C). The reducing amounts of anatase at higher temperatures are studied using FTIR, which suggests the absence of any polymeric chains formed by the chelating agents, which would normally extend anatase-to-rutile transformation temperatures. Differential scanning calorimetry shows that crystalliation occurs before 500 degrees C, providing the crystalline form determined by XRD at 500 degrees C. Increased temperature also resulted in diminished visible light absorption capability, with only the 500 degrees C sample showing significant absorption in the visible region. XPS studies revealed that nitrogen remained within the TiO2 lattice at higher temperatures. Consequent with the reduced visible light absorption capacity, photocatalytic activity also reduced with increased annealing temperature. Degradation kinetics of methylene blue, irradiated with a 60 W house-bulb, resulted in first order degradation rates constants of 0.40 x 10(-2), 0.19 x 10(-2), and 0.22 x 10(-2) min(-1) for 500, 600, and 700 degrees C respectively. Degradation of Degussa P25 was minimal under the same conditions, and that of undoped TiO2 was 0.02 x 10(-2) min(-1). Similarly, using 4-chlorophenol under solar irradiation conditions, the N-doped sample at 500 degrees C substantially out-performed the undoped sample. These results are discussed in the context of the effect of increasing temperature on the nature of the band gap. Crown Copyright (c) 2011 Published by Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available