Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 186, Issue 1, Pages 891-901Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2010.11.091
Keywords
Acid Blue 113; Waste rubber tire; Adsorption kinetics; Adsorption isotherm; Desorption
Categories
Funding
- Ministry of Human Resource Development (MHRD), New Delhi, India
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A mesoporous carbon developed from waste tire rubber, characterized by chemical analysis, FTIR, and SEM studies, was used as an adsorbent for the removal and recovery of a hazardous azo dye, Acid Blue 113. Surface area, porosity, and density were determined. The adsorption of the dye over the prepared adsorbent and a commercial activated carbon was achieved under different pH, adsorbate concentration, sieve size, adsorbent dosage, contact time and temperature conditions. Langmuir and Freundlich adsorption isotherm models were applied and thermodynamic parameters were calculated. Kinetic studies indicated that the adsorption process follow first order kinetics and particle diffusion mechanisms are operative. By percolating the dye solution through fixed-bed columns the bulk removal of the Acid Blue 113 was carried out and necessary parameters were determined to find out the percentage saturation of both the columns. Recovery of the dye was made by eluting 0.1 M NaOH through the column. (C) 2010 Elsevier B.V. All rights reserved.
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