Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 186, Issue 2-3, Pages 1320-1327Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2010.12.006
Keywords
Silkworm exuviae; Methylene blue; Kinetics; Isotherms; Ion-exchange
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Funding
- National Natural Science Foundation of China [20903070]
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In this paper, silkworm exuviae (SE) waste, an agricultural waste available in large quantity in China, was utilized as low-cost adsorbent to remove basic dye (methylene blue, MB) from aqueous solution by adsorption. Kinetic data and sorption equilibrium isotherms were carried out in batch process. The adsorption kinetic experiments revealed that MB adsorption onto SE for different initial dye concentrations all followed pseudo-second order kinetics and were mainly controlled by the film diffusion mechanism. Batch equilibrium results at different temperatures suggest that MB adsorption onto SE can be described perfectly with Freundlich isotherm model compared with Langmuir and D-R isotherm models, and the characteristic parameters for each adsorption isotherm were also determined. Thermodynamic parameters calculated show the adsorption process has been found to be endothermic in nature. The analysis for the values of the mean free energies of adsorption (Ea), the Gibbs free energy (AG) and the effect of ionic strength all demonstrate that the whole adsorption process is mainly dominated by ion-exchange mechanism, which has also been verified by variations in FT-IR spectra and pH value before and after adsorption and desorption studies. The results reveal that SE can be employed as a low-cost alternative to other adsorbents for MB adsorption. (C) 2010 Elsevier B.V. All rights reserved.
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