Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 186, Issue 2-3, Pages 1360-1366Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2010.12.024
Keywords
Defluoridation; Fluoride; Mn-Ce oxide adsorbent; Adsorption capacity; Adsorption mechanism
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Funding
- Program for New Century Excellent Talents in University
- Tsinghua University
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A novel Mn-Ce oxide adsorbent with high sorption capacity for fluoride was prepared via co-precipitation method in this study, and the granular adsorbent was successfully prepared by calcining the mixture of the Mn-Ce powder and pseudo-boehmite. High-resolution transmission electron microscopy (TEM) image showed that the Mn-Ce adsorbent consisted of about 4.5 nm crystals, and X-ray diffraction (XRD) analysis indicated the formation of solid solution by Mn species entering CeO2 lattices. The surface hydroxyl group density on the Mn-Ce adsorbent was determined to be as high as 15.3 mmol g(-1), mainly responsible for its high sorption capacity for fluoride. Sorption isotherms showed that the sorption capacities of fluoride on the powdered and granular adsorbent were 79.5 and 45.5 mg g(-1) respectively at the equilibrium fluoride concentration of 1 mg L-1, much higher than all reported adsorbents. Additionally, the adsorption was fast within the initial 1 h. Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis revealed that the hydroxyl groups on the adsorbent surface were involved in the sorption of fluoride. Both anion exchange and electrostatic interaction were involved in the sorption of fluoride on the Mn-Ce oxide adsorbent. (C) 2010 Elsevier B.V. All rights reserved.
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