4.7 Article

Decreasing polycyclic aromatic hydrocarbons emission from bitumen using alternative bitumen production process

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 185, Issue 2-3, Pages 1156-1161

Publisher

ELSEVIER
DOI: 10.1016/j.jhazmat.2010.10.026

Keywords

Polycyclic aromatic hydrocarbons; Emissions; Occupational exposure; Bitumen modification; Control

Funding

  1. National Iranian Oil Refining and Distribution Company

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In 1988, the National Institute for Occupational Safety and Health (NIOSH) recommended that bitumen fumes should also be considered a potential occupational carcinogen and management practices such as engineering controls should be implemented. Changing the production process of bitumen, as a source control method, was investigated in our study. For the first time, a novel alternative process was used to produce paving grade bitumen with decreased PAH emissions as well as improved bitumen performance grade (PG). Post-consumer latex and natural bitumen (NB) were used as additives to obtain 60/70 modified bitumen directly from the vacuum bottom (VB) without any need for air-blowing. The emissions were produced by a laboratory fume generation rig and were sampled and analyzed by GC-Mass and GC-FID as described in NIOSH method 5515. The PG of the resulting modified 60/70 bitumen in this study covers a wider range of climatic conditions and has higher total resistance against deformation than conventional 60/70 bitumen. The total PAH emissions from modified 60/70 bitumen (100.2619 ng/g) were decreased approximately to 50% of PAHs emitted from conventional 60/70 bitumen (197.696 ng/g). Therefore, it is possible to obtain modified bitumen with lower PAH emissions and better quality than conventional bitumen via additives and without air-blowing. (C) 2010 Elsevier B.V. All rights reserved.

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