Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 177, Issue 1-3, Pages 743-749Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2009.12.094
Keywords
Sono-Fenton reaction; 4A zeolite; alpha-Fe2O3; Support; Ferryl species
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Funding
- National Science Foundation of China [20777015]
- National Basic Research Program of China [2010CB732306, 2007CB613301]
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4A-zeolite supported alpha-Fe2O3 (Fe-4A) was prepared with a hydrothermal-calcination method, and characterized by XRD. Iron oxide in the Fe-4A composite appeared in alpha-Fe2O3 phase and was highly dispersed on the surface of 4A zeolite. Fe-4A composite effectively degraded Orange II under acidic and neutral conditions via sono-Fenton process. 4A-zeolite promoted the production of cavitation bubbles under ultrasonic treatment, while alpha-Fe2O3 promoted the homolysis of oxygen molecule producing hydroxyl radical and high-valent iron-oxo species. Both actions benefited the sono-Fenton reactivity of Fe-4A. Fe-4A-4 composite with a practical alpha-Fe2O3 content of 24.9% showed the maximum sono-Fenton reactivity to Orange II. Dissolved iron ion measurement showed that Fe-4A composite represented a low iron ion dissolution-level, while the repeatability test of recycled Fe-4A showed that Fe-4A composite has high reactivity stability and a long life-time under neutral condition in the sono-Fenton reaction. (C) 2010 Elsevier B.V. All rights reserved.
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