4.7 Article

BiOCl dispersed on NiFe-LDH leads to enhanced photo-degradation of Rhodamine B dye

Journal

APPLIED CLAY SCIENCE
Volume 109, Issue -, Pages 76-82

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.clay.2015.02.009

Keywords

BiOCl; Layered double hydroxides; Photocatalysis; Degradation

Funding

  1. National Natural Science Foundation of China [21477009]
  2. Project of Jiangsu Province Industry-University-Research joint innovation fund [BY2013024-16]
  3. Changzhou Science and Technology Development Program [CJ20140026]

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BiOCl-NiFe-LDH composites were synthesized using NiFe-Cl-LDH and Bi(NO3)(3) as precursors and the composites were characterized by XRD, SEM and FTIR. Photocatalytic degradation of Rhodamine B (RhB) dye was tested with BiOCl-NiFe-LDH composite and NiFe-Cl-LDH and BiOCl materials under the same conditions and the composite was found to be superior to both NiFe-Cl-LDH and BiOCl for RhB degradation. The superior performance of the BiOCl-NiFe-LDH composite was related to better dispersion of BiOCl particles on the surface of NiFe-LDH materials. After three-times of recycling, the RhB degradation efficiencies were 93.3%, 90.1% and 87.9% during the first, second and third cycles, respectively. The BiOCl-NiFe-LDH composite prepared here appears to be an efficient and stable composite photocatalyst, which may have potential applications in wastewater treatment field. (C) 2015 Elsevier B.V. All rights reserved.

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