Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 152, Issue 2, Pages 527-535Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2007.07.015
Keywords
adsorption; iron impregnated coir pith; phosphate removal; sewage
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Iron impregnated coir pith (CP-Fe-I) can be effectively used for the removal of phosphate from aqueous streams and sewage. Iron impregnation on natural coir pith was carried out by drop by drop addition method. The effect of various factors such as pH, initial concentration of phosphate, contact time and adsorbent dose on phosphate adsorption was studied by batch technique. The pH at 3.0 favored the maximum adsorption of phosphate from aqueous solutions. The effect of pH on phosphate adsorption was explained by pH on phosphate speciation in solution and affinity of anions towards the adsorbent sites. A comparative study of the adsorption of phosphate using CP-Fe-I and CP (coir pith) was made and results show that the former one is five to six times more effective than the latter. Kinetic studies revealed that the adsorption process followed a pseudo-second order kinetic model. Adsorption followed Langmuir isotherm model. Column studies were conducted to examine the utility of the investigated adsorbent for the removal of phosphate front continuously flowing aqueous solutions. (c) 2007 Elsevier B.V. All rights reserved.
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