Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 163, Issue -, Pages 23-27Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2014.04.005
Keywords
Palladium-catalyzed; Phenanthridines; Trifluoroacetimidoyl chlorides; C-H functionalization
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Funding
- National Natural Science Foundation of China [U1204205, 21202078, 21272110]
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Highly efficient approaches to obtain 6-trifluoromethyl-phenanthridine derivatives have been realized through the palladium-catalyzed intramolecular C-H bond functionalization of trifluoroacetimidoyl chlorides. The reaction allows the direct formation of C-sp2-C-sp2 bonds via C-H bond functionalization and rapid access to phenanthridine ring systems in moderate to high yields with good functional group tolerance. (C) 2014 Elsevier B.V. All rights reserved.
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