Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 158, Issue -, Pages 44-+Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2013.12.006
Keywords
Deep eutectic mixture; Hexafluoroisopropanol; Aryl/heteroaryl boronic acids; Phenols
Categories
Funding
- National Natural Science Foundation of China [21302014]
- Natural Science Foundation for Colleges and Universities of Jiangsu Province [13KJB150002]
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A new deep eutectic mixture based on choline chloride and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) was prepared and was found to be effective for the rapid transformation of aryl/heteroaryl boronic acids to the corresponding phenols in water using hydrogen peroxide as the oxidant. Broad substrate compatibility, metal- and additive-free conditions as well as reusability of the catalyst made this procedure more environmentally benign. (C) 2013 Elsevier B.V. All rights reserved.
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