Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 155, Issue -, Pages 89-96Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2013.06.009
Keywords
Enaminone; Coordination chemistry; Single-crystal X-ray diffraction; Cyclic voltammetry
Categories
Funding
- Region Rhone-Alpes
- CNRS
- Universite Claude Bernard Lyon 1
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Two tridentate trifluoromethylated enaminones derived from 8-aminoquinoline and 2-aminopyridine L1H and L2H have been designed as ligands that can exhibit multiple coordination centers. Five new complexes 1-5 based on transition metals (Co-II. Ni-II and Zn-II) were prepared and their crystal structure and redox properties have been studied. The role of the trifluoromethyl moieties and their ability to form F center dot center dot center dot H intra- and inter-complexes bonds leading to multidimensional networks have been also featured. (C) 2013 Elsevier B.V. All rights reserved.
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