Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 150, Issue -, Pages 117-123Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2013.02.025
Keywords
C-F activation; Palladium-catalyzed; Polyfluorinated aryl ethers
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Funding
- National Natural Science Foundation of China [21072030]
- Fuzhou University [022318]
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An efficient, ligand-free palladium-catalyzed method for the cross coupling reaction of pentafluor-benzene with phenols was developed. This reaction proceeds via a highly selective C-F bond activation in the 3-position and is compatible with a variety of functional groups, delivering polyfluorinated aryl ethers in moderate to excellent yields. (C) 2013 Elsevier B.V. All rights reserved.
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