Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 143, Issue -, Pages 216-219Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2012.06.008
Keywords
Solkane (R) 365mfc; Fluorine; Trifluoromethylation; Green chemistry; Azomethine imines
Categories
Funding
- Asahi Glass Foundation
- [24105513]
- [22106515]
- [2304]
- Grants-in-Aid for Scientific Research [10J08891, 24105513] Funding Source: KAKEN
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Solkane (R) 365mfc (1,1,1,3,3-pentafluorobutane, CF3CH2CF2CH3) is proven to be an environmental benign alternative solvent for the catalytic enantioselective trifluoromethylation of azomethine imines 1. High chemical yields and enantioselectivities (up to 96% ee) were achieved by employing previously unknown and structurally simple cinchona alkaloid ammonium salt, N-2-iodobenzylcinchoninium bromide 3d as a catalyst. (C) 2012 Elsevier B.V. All rights reserved.
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