Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 131, Issue 11, Pages 1108-1112Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2010.04.005
Keywords
Trifluoromethylation; Organometallic; Copper
Categories
Funding
- Office of Basic Energy Sciences of the U S Department of Energy [DE-FG02-07ER15885]
Ask authors/readers for more resources
New synthetic routes to (NHC)copper-trifluoroacetate and -chlorodifluoroacetate complexes were developed (NHC = N-heterocyclic carbenes) so baseline reactivity patterns could be established for the decarboxylative trifluoromethylation of organic halides In the presence of aryl halides loss of CO2 from these new precursors occurred at 160 C concurrent with the formation of aryl-CF3 (C) 2010 Elsevier BV All rights reserved
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
