Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 131, Issue 2, Pages 270-273Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2009.11.021
Keywords
Transannular cyclizations; 3,7-Dimethylenebicyclo[3.3.1]nonane; Norbornadiene; cis,cis-1,5-Cyclooctadiene; Pentafluorosulfanyl substituent; SF5Cl
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Funding
- Deutsche Forschungsgemeinschaft [436 UKR 113/99/0-1]
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Radical transannular cyclizations of the non-conjugated dienes, such as 3,7-dimethylenebicyclo[3.3.1]nonane and norbornadiene with SF5Cl upon UV-irradiation led to the corresponding SF5-substituted 3,7-noradamantane and nortricyclanes with high yields. Radical reaction of cis,cis-1,5-cyclooctadiene with SF5Cl led to a product of SF5Cl addition to one of the diene double bonds either UV-irradiation or triethylborane were used for radical initiation. (C) 2009 Elsevier B.V. All rights reserved.
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