Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 130, Issue 7, Pages 667-670Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2009.05.003
Keywords
Trifluoromethyltrimethylsilane; Perfluorosulfonic acids; C-F bond activation
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Funding
- Ministry of Education and Science
- Russian Academy of Sciences
- Russian Science Support Foundation
- Russian Foundation for Basic Research [08-03-00428]
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A new property of Me3SiCF3 to undergo C-F bond activation upon interaction with perfluorosulfonic acids is described. The reaction is catalyzed by titanium tetrachloride and affords difluoromethyl perfluorosulfonates in good yields. (C) 2009 Elsevier B.V. All rights reserved.
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