4.3 Article

Green synthesis of methyl trifluoropyruvate catalyzed by solid acids

Journal

JOURNAL OF FLUORINE CHEMISTRY
Volume 129, Issue 5, Pages 332-334

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2008.01.001

Keywords

methyl ester of trifluoropyruvic acid; solid acids; superacids; hexafluoropropylene oxide

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Solid acids - NiSO(4)/Al(2)O(3), Fe(2)(SO(4))(3)/Al(2)O(3) and TiO(2)/SO(4)(2-) -appeared to be effective catalysts for the acid catalyzed synthesis of methyl ester of trifluoropyruvic acid. They are active at 150-180 degrees C. (c) 2008 Elsevier B.V. All rights reserved.

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