Au/Pt/TiO2 catalysts prepared by redox method for the chemoselective 1,2-propanediol oxidation to lactic acid and an NMR spectroscopy approach for analyzing the product mixture

1,2-propanediol obtained from the waste glycerol is the most prominent substrate to produce lactic acid (LA) through the sustainable green catalytic oxidative route. We showed that bimetallic Au/Pt/TiO2 catalysts that could be easily prepared by the redox reaction with preadsorbed hydrogen possessed a high activity in the formation of lactic acid from 1,2-propanediol through selective primary hydroxyl group oxidation by an oxygen air mixture or an air. The most efficient catalyst with the highest TON value was the sample with the lowest Au content. Even the addition of 0.025 wt.% of gold to the 1%Pt/TiO2 catalyst by the redox method resulted in the enhanced 1,2-propanediol conversion up to 96% with the 91% selectivity to LA. The high oxidation activity of the Au/Pt/TiO2 catalysts was ascribed to the strong interaction between the two metals in Au/Pt bimetallic particles and between the bimetallic particles and the support, which was proved by X-ray photoelectron spectroscopy (XPS) analysis, Fourier transform infrared spectroscopy of adsorbed CO (DRIFTS) technique, and temperature programmed reduction method (TPR-H-2). The reaction products were identified and analyzed with the use of 1D and 2D nuclear magnetic resonance spectroscopy (NMR) methods, which also allowed suggesting a plausible up-to-date scheme of 1,2-propanediol catalytic oxidation. (C) 2014 Elsevier B.V. All rights reserved.