4.6 Article

Glycerol steam reforming on bimetallic NiSn/CeO2-MgO-Al2O3 catalysts: Influence of the support, reaction parameters and deactivation/regeneration processes

Journal

APPLIED CATALYSIS A-GENERAL
Volume 492, Issue -, Pages 38-47

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2014.12.029

Keywords

Glycerol steam reforming; Hydrogen production; Reaction parameters; Deactivation/regeneration

Funding

  1. Spanish Ministerio de Economia y Competitividad (MINECO) [ENE2012-374301-C03-01, ENE2013-47880-C3-2-R]
  2. FEDER funds from the European Union
  3. Junta de Andalucia [TEP-8196]

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NiSn bimetallic catalysts supported over Al2O3 modified with different promoter (Mg and/or Ce) were prepared and characterized by powder X-ray diffraction (XRD), N-2 sorptometry, and temperature programmed reduction (TPR). Hydrogen production by glycerol steam reforming over these catalysts was investigated. Among the catalysts, NiSn/AlMgCe catalyst shows the highest hydrogen yield as well as the best stability during the reaction. The effect of reaction temperature, water/glycerol molar ratio and space velocity on the glycerol steam reforming over NiSn/AlMgCe were also investigated. Finally, it was verified that the catalyst can be regenerated by oxidation of carbonaceous deposits. (C) 2014 Elsevier B.V. All rights reserved.

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