4.2 Article

Photodegradation mechanism of deltamethrin and fenvalerate

Journal

JOURNAL OF ENVIRONMENTAL SCIENCES
Volume 22, Issue 7, Pages 1123-1128

Publisher

SCIENCE PRESS
DOI: 10.1016/S1001-0742(09)60227-8

Keywords

pyrethroids; deltamethrin; fenvalerate; photodegradation

Funding

  1. State Key Laboratory of Environmental Chemistry and Ecotoxicology of China [KF2008-08]
  2. Education Department of Hebei [ZH200805]

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To understand the degradation and environmental fate of pyrethroids, the process of their photodegradation under simulated natural conditions was investigated. The results showed that the degradation process follows first-order kinetics. The degradation intermediates were identified with gas chromatography-mass spectrometry. A plausible mechanism was discussed to explain the process. Several influences on degradation process were investigated and reported such as the effects of initial concentration of pyrethroids, total time of light irradiation, solvents, and light source, as well as the effect of a few substances that exist in the environment. This study could be a good reference for the degradation of pyrethroids in practical circumstances.

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