Journal
JOURNAL OF ENVIRONMENTAL SCIENCES
Volume 21, Issue 8, Pages 1028-1035Publisher
SCIENCE PRESS
DOI: 10.1016/S1001-0742(08)62378-5
Keywords
kinetics; nitrate reduction; zero-valent iron; corrosion products; pH
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Funding
- Harbin Institute of Technology [HITQNJS. 2007. 038]
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Although considerable research has been conducted on nitrate reduction by zero-valent iron powder (Fe-0), these studies were mostly operated under anaerobic conditions with invariable pH that was unsuitable for practical application. Without reaction conditions (dissolved oxygen or reaction pH) control, this work aimed at subjecting the kinetics of denitrification by microscale Fe-0 (160-200 mesh) to analysis the factors affecting the denitrification of nitrate and the composition of iron reductive products coating upon the iron surface. Results of the kinetics study have indicated that a higher initial concentration of nitrate would yield a greater reaction rate constant. The reduction rate of nitrate increased with increasing Fe-0 dosage. The reaction can be described as a pseudo-first order reaction with respect to nitrate concentration or Fe-0 dosage. Experimental results also suggested that nitrate reduction by microscale Fe-0 without reaction condition control primarily was an acid-driven surface-mediated process, and the reaction order was 0.65 with respect to hydrogen ion concentration. The analyses of X-ray diffractometry and X-ray photoelectron spectroscopy indicated that a black coating, consisted of Fe2O3, Fe3O4 and FeO(OH), was formed on the surface of iron grains as an iron corrosion product when the system initial pH was lower than 5. The proportion of FeO(OH) increased as reaction time went on, whereas the proportion of Fe3O4 decreased.
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