Seasonal and spatial variability of 210Po, 238U and 239+240Pu levels in the river catchment area assessed by application of neural-network based classification

The present study deals with the application of self-organizing maps (SOM) in order to model, classify and interpret seasonal and spatial variability of Po-210, U-238 and Pu239+240 levels in the Vistula river basin. The data set represents concentration values for 3 alpha emitters (Po-210, U-238 and Pu239+240) measured in surface water samples collected at 19 different sampling locations (8 in major Vistula stream while 11 in right or left Vistula tributaries) during four seasons (winter, spring, summer and autumn) in the framework of a one-year quality monitoring study. The advantages of an SOM algorithm, its classification and visualization ability for environmental data sets, are stressed. The neural-network based classification made it possible to reveal specific patterns related to both seasonal and spatial variability. In the middle and upper part of Vistula catchment as well as in the right-shore tributaries, concentrations of Po-210 and U-238 during summer and winter are the lowest. Concentrations of Po-210 and U-238 increase significantly during spring and autumn in the Vistula river catchment, especially in the delta of Vistula river. High concentration of anthropogenic originated Pu239+240 indicates site-specific character of pollution in two large left-shore tributaries located in the middle part of the Vistula drainage area. Efficient classification of sampling locations could lead to an optimization of river radiochemical sampling networks and to a better tracing of natural and anthropogenic changes along Vistula river stream. (C) 2008 Elsevier Ltd. All rights reserved.