4.7 Article

The study on pyrolysis of oil-based drilling cuttings by microwave and electric heating

Journal

JOURNAL OF ENVIRONMENTAL MANAGEMENT
Volume 228, Issue -, Pages 312-318

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2018.09.040

Keywords

Oil-based drilling cuttings; Microwave heating; Electric heating; Solid residues; Gas products; Liquid products

Funding

  1. National Science and Technology Major Project of China [2016ZX05040-003]
  2. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China) [SLKZZ-2017001]
  3. Fundamental Research Funds for the Central Universities [18CX05001A]

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In this paper, the following questions were investigated: the proportion of mass loss, the mass fraction of oil, the structure, composition and ultimate analysis of solid residues and gas products. By comparing the treatment effect of using both microwave and electric as the source of heat to dispose the oil-based drilling cuttings (OBDC), the advantages of microwave heating treatment were demonstrated. Meanwhile, the composition of liquid products by microwave pyrolysis was analyzed. The results show that the microwave heating is better than electric heating and the former can promote the pyrolysis of petroleum hydrocarbons. The results of component analysis of the liquid products from OBDC by microwave pyrolysis show that C12 similar to C20 components pyrolyze at 500 degrees C. At the same time, a mass of C21 similar to C24 components volatilize. At the temperature above 500 degrees C, the thermal cracking reactions of > C25 components occur and a maximum content of paraffin in liquid products is obtained. As the temperature increases, the components obtained by pyrolysis become more and more complex.

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