Journal
APPLIED CATALYSIS A-GENERAL
Volume 505, Issue -, Pages 70-76Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2015.07.028
Keywords
Iron(III) Schiff base; Singlet oxygen; Photocatalytic degradation; Visible-light
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Funding
- National Natural Science Foundation of China [21407092, 21377067, 21207079, 21177072]
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To degrade organic pollutants in water with hydrogen peroxide (H2O2) under visible light (lambda >= 420 nm), a novel water-insoluble iron Schiff base complex, iron(III)-bis-salicylaldehyde-o-aminophenol (Fe-SAP), was prepared and characterized using NMR, MS, IR, and UV-Vis spectroscopy. Rhodamine B (RhB) and salicylic acid were used as probes to characterize the photocatalytic system. High catalytic activity of Fe-SAP was observed over a wide range of pH values from 3 to 9. Scavenging studies of reactive oxygen species (ROS) and ESR experiments indicate that the primary ROS from photocatalytic conversion of H2O2 is O-1(2), rather than center dot OH. To date, there have been few reports on the generation of O-1(2) by iron organic complexes for the oxidative decomposition of organics. The catalyst stability and reusability are good, most likely because the water-insoluble Fe-SAP is able to reduce the damage to its organic ligands by center dot OH. Given these favorable characteristics, Fe-SAP exhibits excellent potential for practical application in removing refractory organic pollutants and pollutants of emerging concern from water and wastewater. (C) 2015 Elsevier B.V. All rights reserved.
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