4.3 Article

Microstructured Al/Fe2O3/Nitrocellulose Energetic Fibers Realized by Electrospinning

Journal

JOURNAL OF ENERGETIC MATERIALS
Volume 32, Issue 1, Pages 50-59

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/07370652.2012.754515

Keywords

mechanical property; metastable intermolecular composites; microfibers; thermal analysis

Funding

  1. National Natural Science Foundation of China [11002128, 11172276, 11172275]
  2. Science Foundation for Young Scientist of Sichuan Province [2012JQ0038]
  3. State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials from the Southwest University of Science and Technology [11zxfk22]

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At present, metastable intermolecular composites (MICs) have been widely studied for their potential in high-density energetic materials and nanotechnology, but the relatively low-pressure discharge in a short period of time and the oxidation of Al powders have seriously impeded their applications in rocket solid fuels and explosives. In this work, the authors successfully fabricated microstructured Al/Fe2O3/nitrocellulose (Al/Fe2O3/NC) fibers via simple electrospinning, introducing nitrocellulose (NC), a gas generator to MICs. In view of previous reports, wrapping nAl in NC fibers might reduce their further oxidation during storage. In addition, the thermal properties and elastic modulus of NC fibers were measured before and after adding Al/Fe2O3.

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