Journal
JOURNAL OF ELECTRONIC MATERIALS
Volume 42, Issue 7, Pages 1335-1339Publisher
SPRINGER
DOI: 10.1007/s11664-012-2443-5
Keywords
Misfit-layered sulfides; superspace group; structure modulation; thermoelectric properties
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
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Polycrystalline samples of misfit-layered sulfides [Ln(2)S(2)] (p) NbS2 (Ln = lanthanides) have been prepared using the CS2 sulfidation method. Except for Ln = Eu and Lu, single-phase samples were prepared. The compounds consist of an alternate stacking of a trigonal prism-type [NbS2] layer and a double-layered NaCl [rock salt (RS)]-type [Ln(2)S(2)] block, parallel to the c-axis. Three types of stacking modes of the [NbS2] layer and the RS-type block have been confirmed with a (3 + 1)-dimensional superspace group description: two face-centered orthorhombic structures and one face-centered monoclinic structure. Slightly cation-deficient samples with Ln = Yb exhibit the highest Seebeck coefficient S a parts per thousand 59 mu V/K. With electrical resistivity of cm and thermal conductivity of kappa = 0.69 W/Km, this yields a dimensionless figure of merit of ZT = 0.11 at 300 K.
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