Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 657, Issue 1-2, Pages 150-157Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2011.04.008
Keywords
Superoxide ion; Pyridinium; Piperidinium; Pyrrolidinium; Cyclic voltammetry; Chronoamperometry
Categories
Funding
- University of Malaya Centre for Ionic Liquids (UMCiL)
- Research Center at the College of Engineering/King Saud University (Saudi Arabia)
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Electrochemical generation of superoxide ion (O-2(.-)) has been investigated in three room temperature ionic liquids (ILs), based on bis (trifluoromethylsulfonyl) imide anion, [N(Tf)(2)](-), comprising the following cations N-(3-Hydroxypropyl)pyridinium, [HPPy](+), 1-(3-methoxypropyl)-1-methylpiperidinium, [MOPMPip](+), and 1-hexyl-1-methyl-pyrrolidinium, [HMPyrr](+). Cyclic voltammetry (CV) and chrono-amperometry (CA) techniques were used for the analysis of the the electrochemical process. It was found that the generated O-2(.-) was not stable in the IL based on pyridinium cation, [HPPy](+). While a stable CY,was electrochemically generated in [MOPMPip](+) and [HMPyrr](+) based ILs. CV and CA techniques were used to determine the diffusion coefficients of O-2 and solubility of oxygen in the studied ILs as a function of temperature. The diffusional activation energies were then determined. It was found that [HMPyrrr based IL, in general, has higher diffusion coefficient and solubility of O-2 and less diffusional activation energy than [MOPMPip](+) based IL. For our best knowledge, this is the first time piperidinium based ILs has been used for the electrochemical generation of O-2(.-). (C) 2011 Elsevier B.V. All rights reserved.
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