Journal
JOURNAL OF ELASTOMERS AND PLASTICS
Volume 45, Issue 5, Pages 429-444Publisher
SAGE PUBLICATIONS LTD
DOI: 10.1177/0095244312457798
Keywords
Degradation; poly(ethylene terephthalate); recycling; thermal properties; washing
Funding
- Ministry of Science, Education and Sports, Republic of Croatia
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This work demonstrates the poly(ethylene terephthalate) (PET) washing process, which is the very important step in the overall PET recycling procedure. The samples of waste PET bottles were washed in sodium hydroxide at two different temperatures, that is, at 70 and 75 degrees C, at a time intervals of 15 and 30 min. The cleaning efficiency of the washing processes was determined through the identification of the residual impurities and products of PET degradation. The samples before and after the washing procedure were characterized by gas chromatography/mass spectrometry (GC/MS), gel permeation chromatography, thermogravimetric analysis and differential scanning calorimetry. Due to low obtained oligomer molecular masses, it can be concluded that the degradation during all washing processes is not strong. Results show good purity of washed PET, especially at 75 degrees C, due to very low content of adhesives, toxic compounds and formed monomers. The washing process carried out at 75 degrees C for 15 min can be considered as the most successful. It results with low polymer degradation and the removal of the high quantity of contaminants in short time interval.
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