4.4 Article

Nonlinear Oscillations and Multiscale Dynamics in a Closed Chemical Reaction System

Journal

JOURNAL OF DYNAMICS AND DIFFERENTIAL EQUATIONS
Volume 22, Issue 3, Pages 491-507

Publisher

SPRINGER
DOI: 10.1007/s10884-010-9156-3

Keywords

Closed chemical reaction; Reversible Lotka-Volterra system; Multi-scale dynamics; Nonlinear oscillation; Singular perturbation

Funding

  1. Institute for Mathematics and its Applications
  2. NSF [DMS0708331]
  3. NSFC [10428101]
  4. Jilin University

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We investigate the oscillatory chemical dynamics in a closed isothermal reaction system described by the reversible Lotka-Volterra model. This is a three-dimensional, dissipative, singular perturbation to the conservative Lotka-Volterra model, with the free energy serving as a global Lyapunov function. We will show that there is a natural distinction between oscillatory and non-oscillatory regions in the phase space, that is, while orbits ultimately reach the equilibrium in a non-oscillatory fashion, they exhibit damped, oscillatory behaviors as interesting transient dynamics.

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