Journal
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
Volume 31, Issue 12, Pages 1667-1672Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/01932690903297124
Keywords
Aggregation; anionic surfactants; polyglycol ethers; polymer-surfactant interaction
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In order to determine the thermodynamic properties of the aggregation process between sodiun dodecyl sulfate (SDS) and polyglycol ethers (PEG) with average molar mass 35000, 20000, and 10000, the temperature dependence of polymer-surfactant nteraction is used. Surface tension, ionic conductivity, and solubilization methods have been used to quantify the interactions.It was found that the transfer of SDS micelles from aqueous media to aqueous polymer media is more feasible than the reverse. In addition, the hydropholic interaction seems to be important, as opposed to the charge-nonpolar type interaction.
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