Diffusion-induced growth of nanowires: Generalized boundary conditions and self-consistent kinetic equation

In this work, we present a theoretical analysis of the diffusion-induced growth of vapor-liquid-solid nanowires, based on the stationary equations with generalized boundary conditions. We discuss why and how the earlier results are modified when the adatom chemical potential is discontinuous at the nanowire base. Several simplified models for the adatom diffusion flux are discussed, yielding the 1/R-p radius dependence of the length, with p ranging horn 0.5 to 2. The self-consistent approach is used to couple the diffusion transport with the kinetics of 20 nucleation under the droplet. This leads to a new growth equation that contains only two dimensional parameters and the power exponents p and q, where q=1 or 2 depends on the nucleus position. We show that this equation describes the size-dependent depression of the growth rate of narrow nanowires much better than the Gibbs-Thomson correction in several important cases. Overall, our equation fits very well the experimental data on the length-radius correlations of Ill-V and group IV nanowires obtained by different epitaxy techniques. (C) 2014 Elsevier By. All rights reserved.