Journal
JOURNAL OF CRYSTAL GROWTH
Volume 340, Issue 1, Pages 156-165Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jcrysgro.2011.11.082
Keywords
Crystal structure; Growth from high temperature solutions; Tungsten bronzes
Funding
- EU (STREP MaCoMuFI)
- GIS Advanced Materials in Aquitaine (AMA)
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Tetragonal Tungsten Bronze Ferroelectrics (TTB) are currently revisited for the elaboration of new multifunctional materials. Recent studies on Ba(2)LnFeNb(4)O(15) ceramics (Ln = Nd, Sm and Eu) demonstrated that these materials display both ferroelectric and ferromagnetic behaviors at room temperature due to the presence of barium hexaferrite as a secondary phase. In this paper, we report for the first time the growth of Ba(2)LnFeNb(4)O(15) single crystals (Ln = La, Pr, Nd, Sm and Eu) from high temperature solution using LiBO2 flux. Inclusion free millimeter-sized single crystals were successfully grown. Structural and dielectric characterizations were performed and chemical analysis confirmed that the TTB matrix is reluctant to accommodate small rare earth as it was observed for ceramics. A paramagnetic behavior was observed for all compositions, which corroborates the composite nature of the TTB ceramic multiferroics at room temperature, while dielectric measurements on Ln = La and Pr crystals confirmed their relaxor behavior. (C) 2011 Elsevier B.V. All rights reserved.
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