Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 67, Issue 23-24, Pages 3863-3872Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2014.964698
Keywords
Coordination polymers; MONT; Phosphinates; X-ray structure; Copper
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Funding
- Ente Cassa di Risparmio di Firenze project Firenze Hydrolab2
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Given the ability of forming homomeric amide(...)amide dimer by iso-nicotinamide (nda), we postulate the existence of a hydrogen bond equivalent of the iso-reticular metal organic nanotubes (MONT) built by using copper, p,p-diphenylmethylene-diphosphinate (pcp), and bipyridine. We obtained the desired primary arrangement of Cu/pcp/nda consisting of a 1-D chain. Instead of the expected amide/amide dimer, the NH2 groups were engaged in H-bonding networks with the phosphinate ligands in a series of 2-D slabs. The differences and the similarities of the Cu/pcp chains in known MONTs and in the reported structure are also highlighted.
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