Synthesis, crystal structure, fluorescence, electrochemical property, and SOD-like activity of an unexpected nickel(II) complex with a quinazoline-type ligand

An unexpected mononuclear Ni(II) complex, [Ni(L-2)(2)]CH3OH (HL2=1-(2-{[(E)-3,5-dichloro-2-hydroxybenzylidene]amino}phenyl)ethanone oxime), has been synthesized via complexation of Ni(II) acetate tetrahydrate with HL1. HL1 and its corresponding Ni(II) complex were characterized by IR, H-1-NMR spectra, HRMS, as well as by elemental analysis, UV-vis, and emission spectroscopy. The crystal structure of the complex has been determined by single-crystal X-ray diffraction. Each complex links two other molecules into an infinite 1-D chain via intermolecular hydrogen bonds. Moreover, the electrochemical properties of the nickel complex were studied by cyclic voltammetry. Superoxide dismutase-like activities of HL1 and Ni(II) complex were also investigated.