Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 66, Issue 16, Pages 2930-2939Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2013.817570
Keywords
Ionothermal; Polyoxometalate-based frameworks; Topology; Electrochemistry; Electrocatalysis; Photocatalysis
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Funding
- National Natural Science Foundation of China [51203082]
- Guangxi Natural Science Foundation [0832280]
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Using ionic liquid (IL) [Bmim]Br (Bmim=1-butyl-3-methylimidazolium) as solvent has resulted in a polyoxometalate-based metal-organic framework (PMOFs), [Cu(I)Bbi](4)SiW12O40H2O (1) [Bbi=1,1-(1,4-butanediyl)-bis(imidazole)], and was produced via an ionothermal route. Its structure was determined by single-crystal X-ray diffraction. Compound 1 is a 1-D ladder with large voids, resulting in a 3-D supermolecular structure using the classic Keggin-type anion as a second building block. This means utilizing ILs to construct 3-D PMOFs can be efficiently realized. Additionally, electrochemical, electrocatalytic, and photocatalytic properties of 1 were studied.
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