Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 65, Issue 22, Pages 4013-4022Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2012.731049
Keywords
Hydrazone; Molybdenum complex; Crystal structure; Hydrogen-bonding; Sulfoxidation
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Funding
- Jingchu University of Technology
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Two new dioxomolybdenum(VI) complexes, [MoO2L1(CH3OH)] (1) and [MoO2L2(H2O)] (2), where L-1 and L-2 are dianionic form of N'-(2-hydroxy-3-methoxybenzylidene)-4methoxybenzohydrazide and N'-(2-hydroxy-3methoxybenzylidene)-2-hydroxybenzohydrazide, respectively, have been synthesized and structurally characterized by spectroscopic methods and single-crystal X-ray determination. The complexes are mononuclear molybdenum(VI) compounds. Mo in each complex is octahedral. The difference in the substituent groups in the benzohydrazides leads to coordination of different solvent molecules. Crystals of the complexes are stabilized by hydrogen bonds. The complexes are effective catalysts for sulfoxidation.
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