Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 65, Issue 3, Pages 463-473Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2011.648929
Keywords
Metal-organic framework; MIL-101; Supported polyoxometalate; Alkene oxidation; Hydrogen peroxide; Nanoporous material
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Funding
- Center of Excellence of Chemistry of University of Isfahan (CECUI)
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Zinc monosubstituted Keggin heteropolyanion [PZnMo2W9O39](5-) was electrostatically bound to nanocages of MIL-101 polymer matrix. The Zn-POM@MIL-101 catalyst was characterized by XRD, N-2 adsorption, atomic absorption (AAS), and FT-IR spectroscopic methods. The catalytic activity of the new composite material, Zn-POM@MIL-101, was assessed in the oxidation of alkenes using aqueous hydrogen peroxide as oxidant. Zn-POM@MIL-101/H2O2 catalytic system demonstrated good catalytic activity in the oxidation reactions. Zn-POM@MIL-101 was reusable for three catalytic cycles. While the MIL-101 matrix is an active catalyst in these oxidation reactions, the presence of Zn-POM significantly changed the selectivity and reaction times.
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